Napoli went down 3-1 at home to RB Leipzig, Arsenal and AC Milan enjoyed comfortable away wins, and Borussia Dortmund's Michy Batshuayi scored twice to secure a 3-2 victory in Europa League last 32, first leg action
Simeone's side leapfrogged Real Sociedad into fourth on 42 points, while Sevilla stayed third in the standings on 46 after beating Las Palmas 1-0, also on Sunday, thanks to a late strike from substitute Joaquin Correa
A summary of the concluding day's action in the Bundesliga, Serie A, Ligue 1 and Saudi Pro League.
Atletico Madrid sealed top spot in Champions League Group D after second half goals from Frenchmen Kevin Gameiro and Antoine Griezmann but Napoli were held to a 0-0 Champions League draw at home by Dynamo Kiev.
PSG made hard work of beating Strasbourg 4-2 in the French Ligue 1, while Real Madrid registered a comfortable 4-1 win away to Alaves in their opening game.
Alvaro Negredo struck in stoppage-time as stuttering Valencia won 2-1 against his former club Sevilla on Sunday to earn coach Pako Ayesteran victory in his first home game in charge since succeeding Gary Neville.
Liverpool romed into the Europa League final with a 3-0 win over Villarreal on another magical night at Anfield to tee up a showpiece clash with holders Sevilla who swatted away visitors Shakhtar Donetsk 3-1 on Thursday.
Zinedine Zidane got off to a flying start as Real Madrid coach when Gareth Bale hit a hat-trick in a 5-0 win over Deportivo La Coruna on Saturday after a Lionel Messi treble had fired Barcelona to the top of La Liga.
Atletico Madrid's Jackson Martinez scored his first goal for the club when he came off the bench and curled in a superb effort to seal a hard-fought 3-0 victory at Sevilla in La Liga on Sunday.
Borussia Dortmund snatched a late goal at Atalanta to progress with a 1-1 draw, while AC Milan and Atletico Madrid, both with three-goal leads from the away legs, completed the formality of qualifying with 1-0 wins at home on Thursday.
A round-up of Friday's action in La Liga, and Bundesliga.
Second division Mirandes caused an upset by knocking Deportivo La Coruna out of the King's Cup on Tuesday and Sevilla joined them in the quarter-finals after making light work of city rivals Real Betis.
Real Madrid and Atletico each slipped 10 points behind La Liga leaders Barcelona after an intense Madrid derby finished goalless and the Catalans picked up an 11th victory in 12 games by winning 3-0 at Leganes.
Barcelona came through a testing local derby at Espanyol, winning 3-0 to cling to their slender lead at the top of La Liga after rivals Real Madrid had set the challenge by beating Valencia 2-1 in the earlier kick-off.
Real Madrid winger Gareth Bale answered his critics in emphatic style.
A late goal by Toni Kroos sealed victory as Real Madrid defeated an impressive Celta Vigo side 2-1 to win their first home La Liga game of the campaign on Saturday.
Costa turned Juanfran's low cross into the net in the 69th minute for Atletico's third goal in the first leg of the last 16 tie against third division Lleida but immediately limped to the sidelines. He did return to the pitch, however, and completed the game despite bleeding from his knee.
A summary of Saturday's football action across the world.
New Valencia coach Gary Neville remains without a La Liga win after his side twice recovered from a goal down to rescue a fortunate 2-2 draw at home to Getafe on Saturday.
The Portuguese forward put his team on the verge of their third final in four years and took his tally to 103 goals in the competition as he helped Madrid vanquish their neighbours at the Santiago Bernabeu.
IMAGES from the La Liga matches played on Sunday
Rattled by embarrassing domestic defeats, Chelsea looked jittery before Olivier Giroud settled their nerves with a close range tap-in shortly after halftime at StamfordBridge following good work by N'Golo Kante and Willian in the build-up.
Rediff.com gives you a throwback to an eventful 2017, in pictures.
With five titles, Barca are now level with AC Milan on all-time UEFA Super Cup winners list
Portugal international Goncalo Guedes fired Valencia into the lead in the 35th minute with a thumping shot from inside the area which was too powerful for Madrid goalkeeper Keylor Navas.
Liverpool added another fairytale comeback to the history books as they fought back from 3-1 down against Borussia Dortmund to reach the Europa League semi-finals after Dejan Lovren's towering stoppage-time header secured a 4-3 win on Thursday.
An impudent individual goal from Philippe Coutinho steered Liverpool comfortably into the quarter-finals of the Europa League on Thursday after a 1-1 draw at bitter rivals Manchester United completed a 3-1 aggregate win.
Manchester United's hopes of salvaging their season in the Europa League suffered a stinging setback when they lost 2-1 at Danish side Midtjylland in the first leg of their last-32 clash on Thursday.
A summary of sports events and sportspersons, who made news on Tuesday.
Liverpool manager Juergen Klopp enjoyed a satisfying return to Borussia Dortmund as his new side frustrated his former charges and claimed a valuable away goal to draw 1-1 in their Europa League quarter-final, first leg on Thursday.
Manchester City boss Pep Guardiola has warned his side to beware of Monaco's "killers in the box" when they host the principality club in the first leg of their Champions League, last 16 tie on Tuesday.
Luis Suarez was incredulous after being sent off in Barcelona's thrilling King's Cup semi-final second leg with Atletico Madrid on Tuesday, ruling him out of the final in May after playing a pivotal role in getting his team there.
La Liga leaders Real Madrid suffered a surprise 1-0 defeat at mid-table Athletic Bilbao on Saturday after a bullet header from Aritz Aduriz in the first half secured the points.
Cristiano Ronaldo ensured Atletico Madrid fans will have bitter memories of the last local derby at the Vicente Calderon stadium by scoring a hat-trick in a 3-0 win for La Liga leaders Real Madrid on Saturday. Ronaldo's deflected free kick put Real in charge in the 23rd minute in the first meeting of the teams since the Champions League final in May. The prolific Portuguese killed off Atletico's resistance by winning and converting a penalty in the 71st minute and capped a harrowing night for the home side by tapping in the third in the 77th.
Isco scored in the sixth minute of stoppage time as Spain launched an improbable fightback to snatch a 2-2 friendly draw against England with both their goals coming after the 89th minute at Wembley on Tuesday.
Everton have agreed to sign Barcelona's Colombia centre back Yerry Mina for an initial 30.25 million euros ($34.97 million) and have also taken the club's midfielder Andre Gomes on loan, the Spanish champions said on Thursday.
Real Madrid's stuttering season continued as they were reduced to 10 men and then slumped to an 11th La Liga defeat of the campaign by going down 3-1 at Real Sociedad.
News of all that's transpired on and off the football field
Lionel Messi dragged Barcelona back from two goals down by scoring twice to snatch a 2-2 draw at home to Valencia in a thrilling encounter.
Atletico Madrid delayed Barcelona's La Liga title celebrations by beating Valencia 3-2 at home in an entertaining game on Wednesday at a sparsely attended Wanda Metropolitano stadium.